Novo método para a estimativa das constantes de estabilidade de complexos com o edta
The present work describes a new methodology in analytical chemistry, which makes it possible to calculate the stability constant (equilibrium or formation) of the coordination compounds generated between all metallic cations in the periodic table, except for alkali metals (group 1 ) together with...
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| Principais autores: | , |
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| Formato: | article |
| Idioma: | pt_BR |
| Publicado em: |
ICI World of Journals
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| Assuntos: | |
| Endereço do item: | https://repositorio.ufrn.br/handle/123456789/49921 |
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| Resumo: | The present work describes a new methodology in analytical chemistry, which makes it possible to
calculate the stability constant (equilibrium or formation) of the coordination compounds generated between all
metallic cations in the periodic table, except for alkali metals (group 1 ) together with the ethylene diamine
tetraacetic acid binder. The system is simple to use, inexpensive, and allows the knowledge of the size of the
conditional formation constants for all metals coordinated with the complexing agent to be investigated at any
pH value investigated. In addition, the method is also extensive for other binders having the same chemical
reaction property as ethylenediamine tetraacetic acid performs with metal ions in the same stoichiometric
bonding ratio. For the execution of this study, solutions of copper (II) cation was employed, at a concentration of
1.0x10-2 mol L-1 and the complexing agent, also presenting the same concentration of metal. The assay was
conducted in a buffering system consisting of ammonium hydroxide and ammonium chloride salt at a constant
pH of 10.0. The method allows its use in experimental procedures developed both in a chemical laboratory and
in a classroom, used during the theoretical activities. The chelating agent has a wide spectrum of application in
the food product industries, also in the generation of cleaning materials in general, as well as in the photography
industry, textile production, paper manufacture and the like, rubbers and the like, polymers and derivatives,
among other production lines intended for its manufacture for human consumption |
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