Adsorption of chromium ions on oil shale waste
The adsorption of chromium (III) ions onto retorted shale, a waste product of the pyrolysis of oil shale, was investigated as a function of initial pH, temperature, and initial metal ion concentration. Adsorption experiments were carried out in a batch system and the uptake of the metallic ion was...
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ri-123456789-452052021-12-08T13:11:17Z Adsorption of chromium ions on oil shale waste Melo, Marcus Antônio de Freitas Pimentel, Patrícia Mendonça Oliveira, Rosane Maria Pessoa Betânio Melo, Dulce Maria de Araújo Assunção, Ary Leonídio do Carmo Gonzales, Gaspar Chromium (III) Heavy metals Retorted shale Adsorption isotherms Wastewaters The adsorption of chromium (III) ions onto retorted shale, a waste product of the pyrolysis of oil shale, was investigated as a function of initial pH, temperature, and initial metal ion concentration. Adsorption experiments were carried out in a batch system and the uptake of the metallic ion was studied by using an initial concentration range of 200-500 mg L-1. The pseudo-first and pseudo-second order models were used to predict the rate constants of the adsorption system. Both Langmuir and Freundlich models were used to fit the equilibrium data; however, the former resulted in best fitting. Thermodynamic parameters such as enthalpy, free energy, and entropy changes were calculated. The values of such parameters showed that Cr(III) adsorption was favored at high temperatures 2021-12-06T20:03:51Z 2021-12-06T20:03:51Z 2011 article PIMENTEL, P. M.; OLIVEIRA, R. M. P. B.; MELO, D. M. A.; MELO, M. A. F.; ASSUNÇÃO, A. L. C.; GONZALES, G.. ADSORPTION OF CHROMIUM IONS ON OIL SHALE WASTE. Brazilian Journal of Petroleum and Gas, v. 5, p. 65-73, 2011. Disponível em: http://www.portalabpg.org.br/bjpg/index.php/bjpg/article/view/158. Acesso em: 18 ago. 2021. http://dx.doi.org/10.5419/bjpg2011-0008 1982-0593 https://repositorio.ufrn.br/handle/123456789/45205 10.5419/bjpg2011-0008 en application/pdf Brazilian Journal Of Petroleum And Gas |
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Chromium (III) Heavy metals Retorted shale Adsorption isotherms Wastewaters |
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Chromium (III) Heavy metals Retorted shale Adsorption isotherms Wastewaters Melo, Marcus Antônio de Freitas Pimentel, Patrícia Mendonça Oliveira, Rosane Maria Pessoa Betânio Melo, Dulce Maria de Araújo Assunção, Ary Leonídio do Carmo Gonzales, Gaspar Adsorption of chromium ions on oil shale waste |
description |
The adsorption of chromium (III) ions onto retorted shale, a waste product of the pyrolysis of oil shale,
was investigated as a function of initial pH, temperature, and initial metal ion concentration. Adsorption
experiments were carried out in a batch system and the uptake of the metallic ion was studied by using an
initial concentration range of 200-500 mg L-1. The pseudo-first and pseudo-second order models were
used to predict the rate constants of the adsorption system. Both Langmuir and Freundlich models were
used to fit the equilibrium data; however, the former resulted in best fitting. Thermodynamic parameters
such as enthalpy, free energy, and entropy changes were calculated. The values of such parameters
showed that Cr(III) adsorption was favored at high temperatures |
format |
article |
author |
Melo, Marcus Antônio de Freitas Pimentel, Patrícia Mendonça Oliveira, Rosane Maria Pessoa Betânio Melo, Dulce Maria de Araújo Assunção, Ary Leonídio do Carmo Gonzales, Gaspar |
author_facet |
Melo, Marcus Antônio de Freitas Pimentel, Patrícia Mendonça Oliveira, Rosane Maria Pessoa Betânio Melo, Dulce Maria de Araújo Assunção, Ary Leonídio do Carmo Gonzales, Gaspar |
author_sort |
Melo, Marcus Antônio de Freitas |
title |
Adsorption of chromium ions on oil shale waste |
title_short |
Adsorption of chromium ions on oil shale waste |
title_full |
Adsorption of chromium ions on oil shale waste |
title_fullStr |
Adsorption of chromium ions on oil shale waste |
title_full_unstemmed |
Adsorption of chromium ions on oil shale waste |
title_sort |
adsorption of chromium ions on oil shale waste |
publisher |
Brazilian Journal Of Petroleum And Gas |
publishDate |
2021 |
url |
https://repositorio.ufrn.br/handle/123456789/45205 |
work_keys_str_mv |
AT melomarcusantoniodefreitas adsorptionofchromiumionsonoilshalewaste AT pimentelpatriciamendonca adsorptionofchromiumionsonoilshalewaste AT oliveirarosanemariapessoabetanio adsorptionofchromiumionsonoilshalewaste AT melodulcemariadearaujo adsorptionofchromiumionsonoilshalewaste AT assuncaoaryleonidiodocarmo adsorptionofchromiumionsonoilshalewaste AT gonzalesgaspar adsorptionofchromiumionsonoilshalewaste |
_version_ |
1773966200720588800 |