Environmentally friendly synthesis methods to obtain the misfit [Ca2CoO3-d]0.62[CoO2] thermoelectric material
This work reports the microstructural and thermoelectric characterization of the misfit [Ca2CoO3-d]0.62[CoO2] compound obtained by a solid-state synthesis using mollusk shells and a proteic sol-gel method, which uses gelatin as a polymerizing agent. The results clearly demonstrate the capability of...
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Principais autores: | , , , , , , , |
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Formato: | article |
Idioma: | English |
Publicado em: |
Elsevier
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Endereço do item: | https://repositorio.ufrn.br/handle/123456789/32155 |
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Resumo: | This work reports the microstructural and thermoelectric characterization of the misfit [Ca2CoO3-d]0.62[CoO2] compound obtained by a solid-state synthesis using mollusk shells and a proteic sol-gel method, which uses gelatin as a polymerizing agent. The results clearly demonstrate the capability of these routes to produce pure Ca3Co4O9 with plate-like morphology. Sintered ceramic samples show randomly oriented grains and relative densities in the range of 63–67%. The obtained microstructures provide reasonable electrical properties and result in competitive thermoelectric performance for the material prepared by the proteic sol-gel synthesis (P.F. of 205 lW/K2 m at 700 C) |
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