Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders
Ferri-ferromagnetic nanocomposites CoFe 2 O 4 -CoFe 2 were prepared via reduction of the cobalt ferrite CoFe 2 O 4 into a hydrogen atmosphere and by heat treatments. This preparation method yielded powders with relative volume fraction of CoFe 2 O 4 and CoFe 2 in the range 0-0.91. The structure and...
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ri-123456789-292042020-06-14T07:38:04Z Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders Araújo, José Humberto de Machado, Fernando Luis de Araujo Cabral, Francisco de Assis Olímpio Soares, João Maria Rodrigues, Alexandre Ricalde Araujo, Armando Cobalt ferrites Exchange coupling Nanocomposite Material Ferri-ferromagnetic nanocomposites CoFe 2 O 4 -CoFe 2 were prepared via reduction of the cobalt ferrite CoFe 2 O 4 into a hydrogen atmosphere and by heat treatments. This preparation method yielded powders with relative volume fraction of CoFe 2 O 4 and CoFe 2 in the range 0-0.91. The structure and the room temperature magnetization of the samples were analyzed by X-ray diffraction, scanning electron microscope (SEM) and transmission electron microscope (TEM), and by vibrating sample magnetometry, respectively. It was found that the saturation magnetization of the nanocomposite powders increases with the volume fraction of the ferromagnetic phase while their coercivity decreases. The highest value (5 kJ/m 3 ) for the maximum energy product (BH) max was obtained for the sample containing 91% in volume of CoFe 2 . This (BH) max is 19% higher than the value measured in pure CoFe 2 O 4 . The magnetic field dependence of the magnetization did also behave as the nanocomposite powders were single-phase materials. This result indicates that the hard ferrimagnet CoFe 2 O 4 and the soft ferromagnet CoFe 2 are effectively exchange coupled and that their magnetization reverses cooperatively in the range of compositions investigated 2020-06-09T18:55:18Z 2020-06-09T18:55:18Z 2008-12-16 article CABRAL, F. A. O.; MACHADO, F. L. A.; ARAÚJO, José Humberto de; SOARES, J. M.; Ricalde, A.; ARAÚJO, A.. Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders. IEEE Transactions on Magnetics, v. 44, p. 4235-4238, 2008. Disponível em: https://ieeexplore.ieee.org/document/4717406 Acesso em: 09 jun 2020. http://10.1109/TMAG.2008.2001545. 0018-9464 https://repositorio.ufrn.br/jspui/handle/123456789/29204 10.1109/TMAG.2008.2001545 en Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ application/pdf Institute of Electrical and Electronics Engineers |
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Cobalt ferrites Exchange coupling Nanocomposite Material |
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Cobalt ferrites Exchange coupling Nanocomposite Material Araújo, José Humberto de Machado, Fernando Luis de Araujo Cabral, Francisco de Assis Olímpio Soares, João Maria Rodrigues, Alexandre Ricalde Araujo, Armando Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
description |
Ferri-ferromagnetic nanocomposites CoFe 2 O 4 -CoFe 2 were prepared via reduction of the cobalt ferrite CoFe 2 O 4 into a hydrogen atmosphere and by heat treatments. This preparation method yielded powders with relative volume fraction of CoFe 2 O 4 and CoFe 2 in the range 0-0.91. The structure and the room temperature magnetization of the samples were analyzed by X-ray diffraction, scanning electron microscope (SEM) and transmission electron microscope (TEM), and by vibrating sample magnetometry, respectively. It was found that the saturation magnetization of the nanocomposite powders increases with the volume fraction of the ferromagnetic phase while their coercivity decreases. The highest value (5 kJ/m 3 ) for the maximum energy product (BH) max was obtained for the sample containing 91% in volume of CoFe 2 . This (BH) max is 19% higher than the value measured in pure CoFe 2 O 4 . The magnetic field dependence of the magnetization did also behave as the nanocomposite powders were single-phase materials. This result indicates that the hard ferrimagnet CoFe 2 O 4 and the soft ferromagnet CoFe 2 are effectively exchange coupled and that their magnetization reverses cooperatively in the range of compositions investigated |
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article |
author |
Araújo, José Humberto de Machado, Fernando Luis de Araujo Cabral, Francisco de Assis Olímpio Soares, João Maria Rodrigues, Alexandre Ricalde Araujo, Armando |
author_facet |
Araújo, José Humberto de Machado, Fernando Luis de Araujo Cabral, Francisco de Assis Olímpio Soares, João Maria Rodrigues, Alexandre Ricalde Araujo, Armando |
author_sort |
Araújo, José Humberto de |
title |
Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
title_short |
Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
title_full |
Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
title_fullStr |
Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
title_full_unstemmed |
Preparation and magnetic study of the CoFe2O4-CoFe2 nanocomposite powders |
title_sort |
preparation and magnetic study of the cofe2o4-cofe2 nanocomposite powders |
publisher |
Institute of Electrical and Electronics Engineers |
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2020 |
url |
https://repositorio.ufrn.br/jspui/handle/123456789/29204 |
work_keys_str_mv |
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