Síntese, caracterização e estudo das propriedades magnéticas de ortoferritas de lantânio dopadas com manganês
Orthoferrites AFeO3 (A = rare earth) are an important class of perovskite oxides that exhibit weak ferromagnetism. These materials find numerous applications as chemical sensors, cathodes for fuel cells and catalysis, which make them interesting from the standpoint of science and technology. Their s...
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| Format: | doctoralThesis |
| Sprog: | por |
| Udgivet: |
Universidade Federal do Rio Grande do Norte
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| Online adgang: | https://repositorio.ufrn.br/jspui/handle/123456789/17748 |
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| Summary: | Orthoferrites AFeO3 (A = rare earth) are an important class of perovskite oxides that
exhibit weak ferromagnetism. These materials find numerous applications as
chemical sensors, cathodes for fuel cells and catalysis, which make them interesting
from the standpoint of science and technology. Their structural, electrical and
magnetic properties are dependent on many factors such as the preparation method,
heat treatment conditions, chemical composition and replacement of cations in sites
A and/or B. In this paper, LaFe1-xMnxO3 (0 ≤ x ≤ 1) orthoferrites-type was prepared by
Pechini method and Microwave-assisted combustion reaction in order to evaluate the
influence of synthesis route on the formation of oxide, as well as the effect of parcial
replacement of iron by manganese and heat treatment on the magnetic properties.
The precursor powders were calcined at 700°C, 900°C, 1100°C and 1300°C for 4
hours and they were characterized by the techniques: Thermogravimetric analysis
(TGA), X ray diffraction (XRD), Refinement by Rietveld method, Scanning electron
microscopy (SEM), Reduction temperature programmed (RTP) and Magnetic
hysteresis measurements performed at room temperature. According to the XRD
patterns, the formation of perovskite phase with orthorhombic structure was observed
for the systems where 0 ≤ x ≤ 0.5 and rhombohedral for x = 1. The results also
showed a decrease of lattice parameters with the parcial replacement of iron by
manganese and consequently a reduction in cell volume. The hysteresis curves
exhibited weak ferromagnetism for the systems prepared by both synthesis methods.
However, a dependence of magnetization as a function of dopant content was
observed for samples produced by Pechini method. As for the systems prepared by
combustion reaction, it was found that the secondary phases exert a strong influence
on the magnetic behavior |
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